Synthesis of endohedral metallofullerene glycoconjugates by carbene addition.
نویسندگان
چکیده
Endohedral metallofullerene glycoconjugates were synthesized under mild conditions by carbene addition using appropriate glycosylidene-derived diazirine with La(2)@I(h)-C(80). NMR spectroscopic studies revealed that the glycoconjugate consists of two diastereomers of [6,6]-open mono-adducts. The electronic properties were characterized using Vis/NIR absorption spectroscopy and electrochemical measurements. This study demonstrates that glycosylidene carbene is useful to incorporate carbohydrate moieties onto endohedral metallofullerene surfaces.
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ورودعنوان ژورنال:
- Molecules
دوره 16 11 شماره
صفحات -
تاریخ انتشار 2011